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It must be noted that the mechanism of the C–H cleavage step for this electron-rich arene may be distinct from that of the reaction with benzene. Key problems and potential solutions in this field are also discussed. The versatility and practicality of these types of reactions in their current forms are evaluated with respect to the efficiency of catalysis, substrate scope, and operational costs. ![]() Inspired by these precedents, we focused on developing new conditions and reagents that would promote C–H insertion driven by not only by traditional cyclopalladation, but also by the CIPE.įollowing a brief survey of various approaches in Pd-catalyzed C–H activation/C–C bond formation, this review describes the early adventures and recent developments in Pd-catalyzed coupling of C–H bonds with organometallic reagents to form sp 2– sp 2, sp 2– sp 3 and sp 3– sp 3 carbon–carbon bonds. Indeed a pioneering example of ortho-C–H functionalization of acetophenone by a Ru(0) catalyst has been reported. As such, these complexes are, in general, not isolable, even though they are incredibly intriguing from a synthetic perspective. The distinction between the CIPE and directed cyclopalladation is that the thermodynamic stability of the resulting intermediates in the case of the CIPE is generally much lower. We were encouraged on this front by studies using less coordinative oxy-functional groups such as Boc and OMe to direct lithiation through the complex-induced proximity effect (CIPE), a term originally coined by Beak and Snieckus ( Scheme 3). carboxylic acids, ketones, esters, alcohols, etc.). We envisioned ultimately expanding the scope of these reactions to include more synthetically useful oxygen-containing directing groups ( e.g. P.p.s.C–H activation through cyclopalladation or the CIPE So if anyone could please help me out here i'd greatly appreciate it. #C&c generals zero hour mac for macIve tried "the google" but there isint alot of support for mac about this. #C&c generals zero hour mac updateNothing has been edited other than getting ZERO HOUR to update with pacifist. There are no custom maps, no mods, nothing like that. The last time the mismatch occoured it was when i first attacked one of the other teams people? im grasping at straws here These computers have LAN'ed before with this same setup playing unupdated C&C generals. The game runs very nice and fast until it quits, never slows or appears hung-so I don't think its a network issue but im at the end of my rope here ![]() (ps-i have tried updating in the reverse order as well)īoth macs are intel so they *should* be compatible Ran the prepackaged installer as normal to update Generals also. Extract the file Zero Hour.app into the Zero Hour directory Now you have an universal binary which you can run on Intel Mac's"Ħ. #C&c generals zero hour mac PatchGet the file EN_CCG1.0.4_ZH1.0.2_Installer.pkg inside the CC Patch and open it with Pacifist. It will only update Command & Conquer Generals but not Zero Hour 3. "For Zero Hour update follow these steps: 1. followed these instructions to update Zero Hour i found here -> #C&c generals zero hour mac installInstall into existing C&C generals folder per the instructionsĥ. ![]() Mount C&C generals dmg as disc using toastĤ. I have reinstalled both versions multiple times, taking meticulous care to do everything correctly.ġ. I'm trying to play Command and Conquer Zero Hour with another computer on my home wireless network and have done it before with normal C&C.ģ minutes into a LAN game it displays something about " data mismatch loss of sychonization error" and quits. ![]()
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